| Sl.No. | Name of Chief Ministers | From | To | Party |
|---|---|---|---|---|
| 1 | Dayanand Bandodkar | Dec 20, 1963 | Dec 2, 1966 | MGP |
| President's rule | Dec 2, 1966 | Apr 5, 1967 | ||
| 2 | Dayanand Bandodkar | Apr 5, 1967 | Aug 12, 1973 | MGP |
| 3 | Shashikala Kakodkar | Aug 12, 1973 | Apr 27, 1979 | MGP |
| President's rule | Apr 27, 1979 | Jan 16, 1980 | ||
| 4 | Pratapsingh Rane | Jan 16, 1980 | Mar 27, 1990 | (INC)(U) |
| 5 | Churchill Alemao | Mar 27, 1990 | Apr 14, 1990 | Progressive Democratic Front |
| 6 | Dr. Luis Proto Barbosa | Apr 14, 1990 | Dec 14, 1990 | Progressive Democratic Front |
| President's rule | Dec 14, 1990 | Jan 25, 1991 | ||
| 7 | Ravi S. Naik | Jan 25, 1991 | May 18, 1993 | INC |
| 8 | Dr Wilfred de Souza | May 18, 1993 | Apr 2, 1994 | INC |
| 9 | Ravi S. Naik | Apr 2, 1994 | Apr 8, 1994 | INC |
| 10 | Dr Wilfred de Souza | Apr 8, 1994 | Dec 16, 1994 | INC |
| 11 | Pratapsing Rane | Dec 16, 1994 | Jul 30, 1998 | INC |
| 12 | Dr Wilfred de Souza | Jul 30, 1998 | Nov 26, 1998 | Goa Rajiv Congress |
| 13 | Luizinho Faleiro | Nov 26, 1998 | Feb 9, 1999 | INC |
| President's rule | Feb 9, 1999 | Jun 9, 1999 | ||
| 14 | Luizinho Faleiro | Jun 9, 1999 | Nov 24, 1999 | INC |
| 15 | Francisco Sardinha | Nov 24, 1999 | Oct 24, 2000 | Goa People's Congress |
| 16 | Manohar Parrikar | Oct 24, 2000 | Feb 2, 2005 | BJP |
| 17 | Pratapsing Rane | Feb 2, 2005 | Mar 4, 2005 | INC |
| President's rule | Mar 4, 2005 | Jun 7, 2005 | ||
| 18 | Pratapsing Rane | Jun 7, 2005 | Jun 8, 2007 | INC |
| 19 | Digambar Kamat | Jun 8, 2007 | Mar 9, 2012 | INC |
| 20 | Manohar Parrikar | Mar 9, 2012 | Nov 8, 2014 | BJP |
| 21 | Laxmikant Parsekar | Nov 8, 2014 | Mar 14, 2017 | BJP |
| 22 | Manohar Parrikar | Mar 14, 2017 | Present | BJP |
